Perfect softening of the ferroelectric mode in the isotope-exchanged strontium titanate of SrTi18O3 studied by light scattering.

نویسندگان

  • M Takesada
  • M Itoh
  • T Yagi
چکیده

The mode of the isotope-induced ferroelectric strontium titanate shows a perfect softening at the ferroelectric phase transition temperature , where the frequency of the underdamped mode approaches completely to zero within the instrumental resolution. The spectra of the Raman inactive soft mode have been successfully observed owing to local symmetry breaking and by long-term accumulation of the spectral intensity with a high resolution technique. The mechanism of the phase transition is concluded to be an ideal displacive-type accompanied with perfect softening of the Slater-type polar mode. The difference between the soft mode behavior of and indicates that the origin of the quantum paraelectric state of lies in the quantum fluctuation of the oxide octahedron in the perovskite structure.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Domain Redistribution and Ferroelectric Phase Transition in SrTiO3 Under the Influence of an Electric Field and Mechanical Stress

Strontium titanate (SrTiO 3) is one of the best studied substances showing a displacive phase transition [1]. At ambient temperature, it exhibits a cubic perovskite structure with the space group Pm3m. On cooling, a Brillouin zone-boundary softmode drives the second-order transition to an antiferrodis-tortive phase at T C = 105 K. The primary order parameter is the antiphase rotation of TiO 6-o...

متن کامل

Multiferroic domain dynamics in strained strontium titanate.

Multiferroicity can be induced in strontium titanate by applying biaxial strain. Using optical second harmonic generation, we report a transition from 4/mmm to the ferroelectric mm2 phase, followed by a transition to a ferroelastic-ferroelectric mm2 phase in a strontium titanate thin film. Piezoelectric force microscopy is used to study ferroelectric domain switching. Second harmonic generation...

متن کامل

DYNAMICS OF FERROELECTRIC NANO CLUSTER IN BaTiO3 OBSERVED AS A REAL TIME CORRELATION BETWEEN TWO SOFT X-RAY LASER PULSES

We carry out a theoretical investigation to clarify the dynamic property of photo-created nano-sized ferroelectric cluster observed in the paraelectric BaTiO3 as a real time correlation of speckle pattern between two soft X-ray laser pulses, at just above the paraelectricferroelectric phase transition temperature. Based on a model with coupled soft X-ray photon and ferroelectric phonon mode, we...

متن کامل

Synthesis and characterization of Barium Strontium Titanate (BST) micro/nanostructures prepared by improved methods

Nowadays various methods are presented for synthesis of barium strontium titanate (BST) nanopowders with different morphology and properties. Each of these (BST)s has got individual characterization that makes it suitable for a special application. Every method has a special quality, causes it to have preference over the other methods. Low processing temperature is a desired point which most of...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:
  • Physical review letters

دوره 96 22  شماره 

صفحات  -

تاریخ انتشار 2006